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Appearance of ferroelectricity in thin films of incipient ferroelectric

机译:初期铁电薄膜中铁电性的出现

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摘要

The consideration of size-induced ferroelectric-paraelectric phase transitionfor conventional and incipient ferroelectrics thin films with perovskitestructure was carried out in phenomenological theory framework ofGinsburg-Landau-Devonshire. The more general form of surface free energyexpansion that includes intrinsic surface stress tensor, surface piezoelectriceffect and electrostriction as well as quadratic and quartic powers of surfacepolarization has been considered. The analytical expressions for thicknessdependence of transition temperature was derived both for the conventional andincipient ferroelectrics. It was shown that although there is noferroelectricity in the bulk incipient ferroelectrics it appears in thin filmfor the negative extrapolation length that is realized e.g. at positive surfacestress coefficient and negative or zero misfit strain. In our consideration wecame to the conclusion about thickness induced ferroelectricity in incipientferroelectrics KTaO3 at room temperature for the thin enough films. The similarsurface effects can influence strongly on the phase transitions in the thinfilms of another incipient ferroelectrics, SrTiO3.
机译:在Ginsburg-Landau-Devonshire的现象学理论框架内,对具有钙钛矿结构的常规和初生铁电薄膜的尺寸感应铁电-顺电相变进行了研究。已经考虑了表面自由能扩展的更一般形式,包括固有表面应力张量,表面压电效应和电致伸缩以及表面极化的二次和四次幂。对于常规铁电体和初生铁电体,都得出了转变温度随厚度变化的解析表达式。结果表明,尽管在体铁电初生体中没有铁电性,但它在薄膜中表现出负外推长度,这是可以实现的。在正表面应力系数和负或零失配应变下。在我们的考虑中,我们得出了关于室温下初始铁电体KTaO3中足够薄的薄膜的厚度感应铁电的结论。相似的表面效应会严重影响另一种初始铁电体SrTiO3的薄膜中的相变。

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